Calculating EVI from Sentinel-2 Sen2Cor output product

I would stick to 8 and 4. B5 is not in the red spectrum anymore. For NIR you have some freedom. Could be B8 or B9.
Maybe this http://www.met.rdg.ac.uk/~swsgrime/artemis/ch3/ndvi/ndvi.html (pvts.net) gives some insights.
Could be a mistake in the database. You can report this via the Feedback form or via mail.
Values higher 1 can be normal: