I must confess that the input format is not well documented. But it is pretty similar to the output format described in the help (Sentinel Toolbox Application / Import and Export / Extract Pixel Values).
As an example I have attached a file (pin.txt). It is a simple CSV file with tab separated columns.
The columns necessary are Name, Lat and Lon. Optionally a DateTime column or a Date and a Time column can be added. Additional columns are not interpreted but repeated in the ouput file, if the option is enabled.
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